Molar gas constant

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Revision as of 00:36, 2 April 2008 by imported>Milton Beychok (Added a table of R values in various units)
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Values of R Units
8.314472 J·K-1·mol-1
0.082057 L·atm·K-1·mol-1
8.205745 × 10-5 m3·atm·K-1·mol-1
8.314472 L·kPa·K-1·mol-1
8.314472 m3·Pa·K-1·mol-1
62.36367 mmHg·K-1·mol-1
83.14472 L·mbar·K-1·mol-1
10.7316 ft3·psi· °R-1·lb-mol-1
0.7302 ft3·atm·°R-1·lb-mol-1

In chemistry, chemical engineering and physics, the molar gas constant R is a fundamental physical constant which appears in a large number of fundamental equations in the physical sciences, such as the ideal gas law and the Nernst equation. It is equivalent to the the Boltzmann constant (kB) times Avogadro's constant (N): R = kBNA.

It has a defining value of:[1]

R = 8.314472 J · K-1 · mol-1

The gas constant occurs in the ideal gas law as follows:

where:

P is the gas absolute pressure
T is gas absolute) temperature
V is the volume the gas occupies
n is the number of moles of gas
Vm is the molar volume

Notation for the gas constant

The gas constant defined in this article is the universal gas constant, , that applies to any gas. There is also a specific gas constant, which can be denoted as . The specific gas constant is defined as where is the molecular weight.

Unfortunately, many authors in the technical literature sometimes use as the specific gas constant without denoting it as such or stating that it is the specific gas constant. This can and does lead to confusion for many readers.

Reference

  1. Molar gas constant Obtained on 16 December, 2007 from the NIST website