Coffee

(CC) Photo: Robert W. King
A cafe mocha (made from compressed espresso grounds, combined with steamed milk and chocolate sauce) with whipped cream on top and a glazed donut.

Regardless of its preparation, coffee is one of the most popular and widely consumed beverages in the world today. It is well-known to contain the stimulant caffeine as well as antioxidants and other plant chemicals (phytochemicals). Coffee is typically brewed from roasted beans (actually seeds) harvested from cherries grown from the genus of plants known as Coffea. There are six species of tropical Coffea trees, of which there are as many as 6,000 known varieties.

The outer skin of the coffee cherry is the exocarp; beneath it is a thin layer of pulp known as the mesocarp, then a slimy layer called parenchyma. The beans within the parenchyma are covered in the thin layer referred to as the endocarp. Inside the endocarp are two beans, usually positioned next to each other, divided by a membrane called the spermoderm.

Although the availability of coffee is almost ubiquitous, Coffea trees can only be grown in certain climates. The most effective places to grow coffee are in tropical or sub-tropical environments at high altitudes. Because of this, distinct places in the world are prime for Coffea cultivation: Brazil, Colombia, India, Indonesia, Mexico, Puerto Rico, and Vietnam are the top Coffea growing and exporting countries.

Coffee can be prepared and served in a number of ways. A common Western method calls for roasted beans to be ground (coarse) and then placed into a paper filter, where hot water is then strained into the filter, soaking the grounds, from which the coffee drips into a coffee pot. The appliances that produce coffee in this way are known as drip-style coffee makers, or "drip-pots" in the USA, and as coffee filter machines in Europe.

(CC) Photo: Julius Schorzman
A cup of coffee

Greek, Turkish and other coffees from the Ottoman period are made by rapidly boiling finely-ground roasted beans, along with the appropriate amount of sugar, in a special small metal pan. The resulting mix is poured into a small cup, of which only the upper liquid is drunk. The bottom third or so of the cup contains coffee grounds.

A popular, originally Italian, method of preparing coffee is to finely grind heavily roasted beans and compress them into a metal filter. Hot water is then forced through the filter, producing a concentrated form of coffee that is very dark in color and contains a higher percentage of caffeine per milliliter compared to other forms. This is known simply as espresso and is often served in quantities of ounces, or "shots." Espresso machines can create pressure by either heating water up to its boiling point, creating steam to produce the concentrate, or through a pump that injects water into the compressed grounds. The amount of compression (measured in pounds/square inch (psi)) varies between the different styles of appliances.

Caffeine and the development of decaffeinated coffee in the West

Despite naturally-occurring differences in Coffea plants, there is a commercial demand for decaffeinated coffee. The two most common types of beans sold world-wide, Arabica (Coffea arabica) and Robusta (Coffea robusta), do contain different levels of naturally occurring caffeine, the latter typically having more than the former. However, "decaf" (as its commonly referred to) is produced by one of two post-harvest methods. In the first, known as indirect, the beans are soaked in hot water to dissolve the caffeine. The water is then treated with a chemical solvent to remove the caffeine. In order to maintain the taste or flavour constituents, the water is resprayed back into the beans. The direct method involves soaking the beans in the chemically treated water, removing the solvent from the water, and then allowing the beans to resoak.

There are four different chemical processes by which coffee can be decaffeinated:

• Methylene chloride (DCM): DCM is involved in the direct method of decaffeination. The disadvantages to using DCM are that it is a carcinogenic, and an ozone-depleting gas.
• Ethyl Acetate: Ethyl acetate exists in fruit naturally, but for commercial decaffeination it is produced from ethyl alcohol and acetic acid. The resulting product can be carcinogenic.
• Supercritical Carbon Dioxide: the raw coffee beans are exposed to pressurized, liquid carbon dioxide. In an evaporator, the caffeine is drawn out by the carbon dioxide and precipitates; after a period of evaporation and recondensation, the mixture is recirculated into the coffee.
• Swiss Water Process: Devised by Kraft Foods Inc, this is a chemical free process. Beans are first soaked in water, which absorbs the caffeine content. The water is passed through carbon filters which process out the caffeine. A fresh batch of beans is then soaked in the caffeine-free water, which still retains much of the flavour constituents from the previous soak.