Steam

(PD) Photo: Gretar Ívarsson
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Steam is the vapor (gaseous) phase of water (H₂O). When the steam does not contain any liquid water, it is known as dry steam and it is completely colorless. However, when the steam contains tiny droplets of condensed liquid water, it appears to the eye as a white cloud (see the steam being vented from a geothermal power plant in the adjacent photograph).

What is very often referred to as smoke from cooling towers and other vents in industrial facilities is water vapor which has partially condensed and is mistaken to be white smoke.

Steam is manufactured in industrial processes by the boiling and vaporization of liquid water. It also occurs naturally by being vented from volcanoes, fumaroles, geysers and other geothermal sources.

Steam has a great many industrial and domestic uses. Probably the most important and by far the largest use of steam is in nuclear, fossil fuel and geothermal power plants.

Types of steam

(CC) Diagram: Milton Beychok

As shown in the adjacent diagram, there are three types of steam:

• Wet steam: A mixture of water plus steam (liquid plus vapor) at the boiling point temperature of water at a given pressure.
• Dry steam: Steam, at the given pressure, that contains no water (also referred to as saturated steam).
• Superheated steam: Dry steam, at the given pressure, that has been heated to a temperature higher than the boiling point of water at that pressure.

Referring to the adjacent drawing again, water is converted into wet, dry saturated or superheated steam in three steps:

• Water at point 1 is heated to its boiling point at the given pressure of point 2 (the dark blue line). At that point the water is then referred to as saturated water. The amount of heat added between points 1 and 2 is called sensible heat.

• The water is further heated at constant pressure (the red isobar from point 2 to point 3) to form wet steam. When it is completely vaporized (at point 3), it is then dry saturated steam. The amount of heat required to completely vaporize the water is called the heat of vaporization and denoted as H_v or H_vap.

• The dry saturated steam is yet further heated at constant pressure (the red isobar from point 3 to point 4). The steam is then referred to as superheated steam. The amount of heat added to superheat the dry saturated steam is also called sensible heat.

• It should be noted that the points 2 and 3 are at the same boiling point temperature and pressure and also that, at those conditions, the liquid and the steam (whether wet or dry) are in equilibrium with each other.

Uses

Electricity generation

The worldwide capacity of electrical power generation by conventional coal-fired power plants currently amounts to about 800,000 MW and the worldwide capacity of nuclear power generation amounts to about 370,000 MW. That amounts to a total of 1,170,000 MW of worldwide generation, most of which involves the use of superheated steam to drive the turbines that spin the electrical generators (see the adjacent schematic diagram).

Assuming an overall thermal efficiency of 34%, a steam generator (boiler) efficiency of 75 to 85% and an electrical generator efficiency of 98.5%, a conventional coal-fired power plant would use superheated steam at a rate of 3.47 to 3.93 (t/h) per MW of power output. Thus, a 1000 MW power plant would use 3,470 to 3,930 metric tons (tonnes) of steam per hour and the steam used by the 1,170,000 MW of worldwide power generation by coal-fired and nuclear power plants might be as much as 4,000,000 to 4,600,000 metric tons of steam per hour.

The diagrams below schematically depict the equipment used in a conventional fuel-fired steam to electric power plant as well as the temperature-entropy (T-S) diagram of the corresponding Rankine cycle. A nuclear power plant differs only to the extent that the heat required by the boiler is provided by heat derived from a nuclear reactor.

(PD) Diagram: Milton Beychok

(PD) Diagram: Milton Beychok

Cogeneration of heat and power]]

Cogeneration is also referred to as combined heat and power or CHP. In electrical power generation, the turbine exhaust steam is typically condensed and returned to the boiler for re-use. However, in one form of cogeneration, all or part of the turbine exhaust steam is distributed through a district heating system to heat buildings rather than being condensed. The world's biggest steam cogeneration system is the district heating system which distributes steam from seven cogeneration plants to provide heating for 100,000 buildings in the city of New York.

Steam engines

As an overall definition, a steam engine is an engine that uses steam to perform mechanical work. By that definition, steam turbines are steam engines. However, this section describes steam engines that use the expansion of steam to move a piston that performs work. Such steam engines were the driving force behind the Industrial Revolution of the 18th century and gained widespread commercial use for driving machinery in factories, powering water pumping stations and transport application such as railway locomotives, steamships and road vehicles. The use of tractors driven by steam engines led to an increase in the land available for agricultural cultivation.

Although largely replaced by steam turbines, stationary reciprocating steam engines are still used in industry and elsewhere for driving pumps, gas compressors and other types of machinery.

Uses in industrial process facilities

A great many processes in petroleum refineries, natural gas processing plants and petrochemical plants use steam as:

• A heat source in heat exchangers designed to increase the temperature of distillation column feedstocks.

• A heat source for distillation column reboilers.

• A heat source injected directly into various distillation columns known as steam strippers and side-cut strippers to provide the required distillation heat.

• The motive force for injectors and ejectors.

• A heat source for stripping the spent catalyst in fluid catalytic cracking processes of volatile hydrocarbons.

• A medium for purging of process vessels such as petroleum coke drums in delayed coking units.

• A reactant in catalytic steam-methane reformers for the industrial production of hydrogen.

• A diluent in steam cracking units which produce petrochemical feedstocks such as ethylene and other olefins from natural gas and petroleum hydrocarbons such as methane, ethane, propane, butanes, petroleum naphtha and petroleum gas oil.

• The heat source for evaporation processes in sugar refining and in water desalination processes.

• A heat source flowing through tubular coils installed inside storage tanks to heat certain stored liquids.

Other uses

Sterilization

An autoclave, which uses steam under pressure, is used in microbiology laboratories and similar environments for sterilization.

Agricultural

In agriculture, steam is used for soil sterilization to avoid the use of harmful chemical agents and increase soil health.

Commercial and domestic uses

Steam's capability to transfer heat is also used in the home as well as commercial facilities for pressure cookers, steam cleaning of fabrics and carpets, steam ironing and for heating of buildings.

Steam tables and Mollier diagrams

Steam tables provide tabulated thermodynamic data for the liquid and vapor phases of water. The table below is only an example of the type of data provided. In a complete set of steam tables, the table would provide data in temperature increments of 1 °C. The complete steam tables would also provide a similar "Saturated Steam:Pressure Table" in which the first column would have pressure values and the second column would be temperature values. Most steam tables include tabulated thermodynamic data for superheated steam as well.

Saturated Steam:Temperature Table

T °C	P bar	P kPa	ρL kg/m3	ρV kg/m3	HL J/g	HVap J/g	HV J/g	SL J/(g·K)	SVap J/(g·K)	SV J/(g·K)
10	0.012282	1.2282	999.65	0.00941	42.02	2477.2	2519.2	0.15109	8.7487	8.8998
20	0.023393	2.3393	998.19	0.01731	83.91	2453.5	2537.4	0.29648	8.3695	8.6660
30	0.042470	4.2470	995.61	0.03042	125.73	2429.8	2555.5	0.43675	8.0152	8.4520
40	0.073849	7.3849	992.18	0.05124	167.53	2406.0	2573.5	0.57240	7.6831	8.2555
50	0.12352	12.352	988.00	0.08315	209.34	2381.9	2591.3	0.70381	7.3710	8.0748
100	1.0142	101.42	958.35	0.5982	419.17	2256.4	2675.6	1.3072	6.0469	7.3541
150	4.7616	476.16	917.01	2.5481	632.18	2113.7	2745.9	1.8418	4.9953	6.8371
200	15.549	1554.9	864.66	7.8610	852.27	1939.7	2792.0	2.3305	4.0996	6.4302
250	39.762	3976.2	798.89	19.967	1085.8	1715.2	2800.9	2.7935	3.2785	6.0721
300	85.879	8587.9	712.14	46.168	1345.0	1404.6	2749.6	3.2552	2.4507	5.7059
Symbols: P = absolute pressure   ρL = liquid density   ρV = vapor density HL = liquid specific enthalpy   HVap = enthalpy of vaporization   HV = vapor specific enthalpy SL = liquid specific entropy   SVap = entropy of vaporization   SV = vapor specific entropy

Mollier diagrams are graphical representations of the thermodynamic properties of materials involving "Enthalpy" as one of the coordinates. Mollier diagrams are named after Richard Mollier (1863 - 1935), a professor at Dresden University in Germany, who pioneered the graphical display of the relationship of temperature, pressure, enthalpy, entropy and volume of steam (as well as for moist air) that has aided in the teaching of thermodynamics to many generations of engineers. His enthalpy-entropy (H-S) diagram for steam was first published in 1904.

Mollier diagrams are routinely used to visualize the working cycles of thermodynamic systems involved with the chemical engineering process design of power plants (fossil or nuclear), gas compressors, steam turbines, refrigeration systems and air conditioning.

A sample Mollier diagram for steam is presented below and others are available online:

(GNU) Image: Markus Schweiss
Mollier H-S Diagram for Water-Steam