Vacuum (quantum electrodynamic)

This article is about Vacuum (quantum electrodynamic). For other uses of the term Vacuum, please see Vacuum (disambiguation).

The term quantum electrodynamic vacuum, or QED, refers to the ground state of the electromagnetic field, which is subject to fluctuations about a dormant zero average-field condition: Here is a description of the quantum vacuum:

“The quantum theory asserts that a vacuum, even the most perfect vacuum devoid of any matter, is not really empty. Rather the quantum vacuum can be depicted as a sea of continuously appearing and disappearing [pairs of] particles that manifest themselves in the apparent jostling of particles that is quite distinct form their thermal motions. These particles are ‘virtual’, as opposed to real, particles. ...At any given instant, the vacuum is full of such virtual pairs, which leave their signature behind, by affecting the energy levels of atoms.”

-Joseph Silk On the shores of the unknown, p. 62

It is sometimes attempted to provide an intuitive picture of virtual particles based upon the Heisenberg energy-time uncertainty principle:

$\Delta E\Delta t\geq \hbar \ ,$

arguing along the lines that the short lifetime of virtual particles allows the "borrowing" of large energies from the vacuum and thus permits particle generation for short times. However, such interpretations of the energy-time uncertainty relation are not generally accepted, and the many interpretations of this principle form a very long and continuing subject.

Quantization of the fields

The Heisenberg uncertainty principle does not allow a particle to exist in a state in which the particle is simultaneously at a fixed location, say the origin of coordinates, and has also zero momentum. Instead the particle has a range of momentum and spread in location attributable to quantum fluctuations; if confined, it has a zero-point energy.

An uncertainty principle applies to all quantum mechanical operators that do not commute. In particular, it applies also to the electromagnetic field. A digression follows to flesh out the role of commutators for the electromagnetic field.

The standard approach to the quantization of the electromagnetic field begins by introducing a vector potential A and a scalar potential V to represent the basic electromagnetic electric field E and magnetic field B using the relations: ${\begin{aligned}\mathbf {B} &=\mathbf {\nabla \times A} ,\\\mathbf {E} &=-\mathbf {A-\nabla } V\ .\end{aligned}}$ The vector potential is not completely determined by these relations, leaving open a so-called gauge freedom. Resolving this ambiguity using the Coulomb gauge leads to a description of the electromagnetic fields in the absence of charges in terms of the vector potential and the momentum field Π, given by: $\mathbf {\Pi } =\varepsilon _{0}{\frac {\partial }{\partial t}}\mathbf {A} \ ,$ where ε0 is the electric constant of the SI units. Quantization is achieved by insisting that the momentum field and the vector potential do not commute.

Because of the non-commutation of field variables, the variances of the fields cannot be zero, although their averages are zero. The electromagnetic field has therefore a zero-point energy, and a lowest quantum state. The interaction of an excited atom with this lowest quantum state of the electromagnetic field is what leads to spontaneous emission, the transition of an excited atom to a state of lower energy by emission of a photon even when no external perturbation of the atom is present.

Electromagnetic properties

As a result of quantization, the quantum electrodynamic vacuum can be considered as a dielectric medium, and is capable of vacuum polarization. In particular, the force law between charged particles is affected. The electrical permittivity of quantum electrodynamic vacuum can be calculated, and it differs slightly from the simple ε₀ of the classical vacuum. Likewise, its permeability can be calculated and differs slightly from μ₀. This medium is a dielectric with relative dielectric constant > 1, and is diamagnetic, with relative magnetic permeability < 1. Under some extreme circumstances (for example, in the very high fields found in the exterior regions of pulsars ), the quantum electrodynamic vacuum is thought to exhibit nonlinearity in the fields. Calculations also indicate birefringence and dichroism at high fields.

Attainability

A perfect vacuum is itself only realizable in principle. It is an idealization, like absolute zero for temperature, that can be approached, but never actually realized:

“One reason [a vacuum is not empty] is that the walls of a vacuum chamber emit light in the form of black-body radiation...If this soup of photons is in thermodynamic equilibrium with the walls, it can be said to have a particular temperature, as well as a pressure. Another reason that perfect vacuum is impossible is the Heisenberg uncertainty principle which states that no particles can ever have an exact position ...Each atom exists as a probability function of space, which has a certain nonzero value everywhere in a given volume. ...More fundamentally, quantum mechanics predicts ...a correction to the energy called the zero-point energy [that] consists of energies of virtual particles that have a brief existence. This is called vacuum fluctuation.” Luciano Boi, "Creating the physical world ex nihilo?" p. 55