Bohr radius: Difference between revisions
imported>Paul Wormer No edit summary |
imported>Paul Wormer No edit summary |
||
| Line 1: | Line 1: | ||
{{subpages}} | {{subpages}} | ||
[[Niels Bohr]]'s theory | [[Niels Bohr|Bohr]]'s theory of the [[hydrogen]] atom (1913) predicts the existence of a smallest orbit for the [[electron]] circulating the hydrogen [[nucleus]]. Today the radius of this orbit is called the '''Bohr radius'''. It is usually indicated by ''a''<sub>0</sub>. | ||
In the old quantum theory of Bohr and [[Arnold Sommerfeld]], as well as in the new quantum theory of [[Werner Heisenberg]] and [[Erwin Schrödinger]] the radius is given by | |||
:<math> | :<math> | ||
a_0 = \frac{4\pi \epsilon_0 \hbar^2}{\mu e^2} \approx 0.529\,177\,208\,59\cdot 10^{-10}\; \mathrm{m} | a_0 = \frac{4\pi \epsilon_0 \hbar^2}{\mu e^2} \approx 0.529\,177\,208\,59\cdot 10^{-10}\; \mathrm{m} | ||
</math> | </math> | ||
where ε<sub>0</sub> is the [[vacuum permittivity]] (electric constant), <math>\hbar</math> | where ε<sub>0</sub> is the [[vacuum permittivity]] (electric constant), <math>\hbar</math> | ||
is [[Planck's constant|Planck's reduced constant]], μ is the [[reduced mass]] of the hydrogen atom (is equal to the [[electron mass]] when the [[proton mass]] may supposed to be infinite; for the numerical value this is | is [[Planck's constant|Planck's reduced constant]], μ is the [[reduced mass]] of the hydrogen atom (is equal to the [[electron mass]] when the [[proton mass]] may supposed to be infinite; for the numerical value given this assumption is made) and ''e'' is the [[elementary charge|charge of the electron]]. | ||
In [[quantum mechanics]], ''a''<sub>0</sub> appears in the | In [[quantum mechanics]], ''a''<sub>0</sub> appears as the maximum in the radial distribution associated with the electronic [[wave function]] of lowest energy of the [[hydrogen-like atom|hydrogen atom]], the so-called 1s [[atomic orbital]]. That is, ''a''<sub>0</sub> is the position of the maximum in the radial distribution 4π''r''<sup> 2</sup> |Ψ<sub>1s</sub>(''r'') |<sup>2</sup>. | ||
''a''<sub>0</sub> is the position of the maximum in the radial distribution 4π''r''<sup> 2</sup> |Ψ<sub>1s</sub>(''r'') |<sup>2</sup>. | |||
==External link== | ==External link== | ||
[http://physics.nist.gov/cgi-bin/cuu/Value?eqbohrrada0 NIST value for bohr radius] | [http://physics.nist.gov/cgi-bin/cuu/Value?eqbohrrada0 NIST value for bohr radius] | ||
Revision as of 09:37, 29 August 2009
Bohr's theory of the hydrogen atom (1913) predicts the existence of a smallest orbit for the electron circulating the hydrogen nucleus. Today the radius of this orbit is called the Bohr radius. It is usually indicated by a0.
In the old quantum theory of Bohr and Arnold Sommerfeld, as well as in the new quantum theory of Werner Heisenberg and Erwin Schrödinger the radius is given by
where ε0 is the vacuum permittivity (electric constant), is Planck's reduced constant, μ is the reduced mass of the hydrogen atom (is equal to the electron mass when the proton mass may supposed to be infinite; for the numerical value given this assumption is made) and e is the charge of the electron.
In quantum mechanics, a0 appears as the maximum in the radial distribution associated with the electronic wave function of lowest energy of the hydrogen atom, the so-called 1s atomic orbital. That is, a0 is the position of the maximum in the radial distribution 4πr 2 |Ψ1s(r) |2.