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== '''[[Ideal gas law]]''' ==
== '''[[Hausdorff dimension]]''' ==
''by  [[User:Milton Beychok|Milton Beychok]] and [[User:Paul Wormer|Paul Wormer]] (and [[User:Daniel Mietchen|Daniel Mietchen]] and [[User:David E. Volk|David E. Volk]])
''by  [[User:Melchior Grutzmann|Melchior Grutzmann]] (and [[User:Brandon Piercy|Brandon Piercy]] and [[User:Hendra I. Nurdin|Hendra I. Nurdin]])


----
----
{|  class="wikitable" style="float: right;"
! Values of ''R''
! Units
|-
| 8.314472
|  [[Joule|J]]·[[Kelvin|K]]<sup>-1</sup>·[[Mole (unit)|mol]]<sup>-1</sup>
|-
| 0.082057
| [[Liter|L]]·[[atmosphere (unit)|atm]]·K<sup>-1</sup>·mol<sup>-1</sup>
|-
| 8.205745 × 10<sup>-5</sup>
|  [[metre|m]]<sup>3</sup>·atm·K<sup>-1</sup>·mol<sup>-1</sup>
|-
| 8.314472
| L·k[[Pascal (unit)|Pa]]·K<sup>-1</sup>·mol<sup>-1</sup>
|-
| 8.314472
| m<sup>3</sup>·Pa·K<sup>-1</sup>·mol<sup>-1</sup>
|-
| 62.36367
| L·[[mmHg]]·K<sup>-1</sup>·mol<sup>-1</sup>
|-
| 62.36367
| L·[[torr]]·K<sup>-1</sup>·mol<sup>-1</sup>
|-
| 83.14472
| L·m[[Bar (unit)|bar]]·K<sup>-1</sup>·mol<sup>-1</sup>
|-
| 10.7316
| [[Foot (unit)|ft]]<sup>3</sup>·[[Psi (unit)|psi]]· [[Rankine scale|°R]]<sup>-1</sup>·[[lb-mol]]<sup>-1</sup>
|-
|  0.73024
| ft<sup>3</sup>·atm·°R<sup>-1</sup>·lb-mol<sup>-1</sup>
|}


The '''[[ideal gas law]]''' is the [[equation of state]] of an '''ideal gas''' (also known as a '''perfect gas''') that relates its [[Pressure#Absolute pressure versus gauge pressure|absolute pressure]] ''p'' to its [[temperature|absolute temperature]] ''T''. Further parameters that enter the equation are the [[volume]] ''V'' of the container holding the gas and the [[amount of substance|amount]] ''n'' (in [[mole (unit)|moles]]) of gas contained in there. The law reads
In [[mathematics]], the '''Hausdorff dimension''' is a way of defining a possibly fractional exponent for all  figures in a [[metric space]] such that the dimension describes partially the amount to that the set fills the space around it.  For example, a [[plane (geometry)|plane]] would have a Hausdorff dimension of 2, because it fills a 2-parameter subset. However, it would not make sense to give the [[Sierpiński triangle]] [[fractal]] a dimension of 2, since it does not fully occupy the 2-dimensional realm. The Hausdorff dimension describes this mathematically by measuring the size of the setFor self-similar sets there is a relationship to the number of self-similar subsets and their scale.
:<math> pV = nRT \,</math>
where ''R'' is the [[molar gas constant]], defined as the product of the [[Boltzmann constant]] ''k''<sub>B</sub> and  [[Avogadro's constant]] ''N''<sub>A</sub>
:<math>
R \equiv N_\mathrm{A} k_\mathrm{B}
</math>
Currently, the most accurate value of R is:<ref>[http://physics.nist.gov/cgi-bin/cuu/Value?r Molar gas constant] Obtained from the [[NIST]] website. [http://www.webcitation.org/query?url=http%3A%2F%2Fphysics.nist.gov%2Fcgi-bin%2Fcuu%2FValue%3Fr&date=2009-01-03 (Archived by WebCite® at http://www.webcitation.org/5dZ3JDcYN on Jan 3, 2009)]</ref> 8.314472 ± 0.000015 J·K<sup>-1</sup>·mol<sup>-1</sup>.


The law applies to ''ideal gases'' which are hypothetical gases that consist of [[molecules]]<ref>Atoms may be seen as mono-atomic molecules.</ref> that do not interact, i.e., that move through the container independently of each other.  In contrast to what is sometimes stated (see, e.g., Ref.<ref>[http://en.wikipedia.org/w/index.php?oldid=261421829 Wikipedia: Ideal gas law] Version of January 2, 2009</ref>) an ideal gas does not necessarily consist of [[point particle]]s without internal structure, but may be formed by polyatomic molecules with internal rotational, vibrational, and electronic [[degrees of freedom]]. The ideal gas law describes the motion of the [[center of mass|centers of mass]] of the molecules and, indeed, mass centers may be seen as structureless point masses. However, for other properties of ideal gases, such as [[entropy (thermodynamics)|entropy]], the internal structure may play a role.
=== Informal definition ===
Intuitively, the dimension of a set is the number of independent parameters one has to pick in order to fix a point.  This is made rigorously with the notion of ''d''-dimensional (topological) [[manifold]] which are particularly regular sets. The problem with the classical notion is that you can easily break up the digits of a real number to map it bijectively to two (or ''d'') real numbers. The example of space filling curves shows that it is even possible to do this in a continuous (but non-bijective) way.


The ideal gas law is a useful approximation for calculating temperatures, volumes, pressures or amount of substance for many gases over a wide range of values, as long as the temperatures and pressures are far from the values where [[condensation]] or [[sublimation]] occur.
The notion of Hausdorff dimension refines this notion of dimension such that the dimension can be any non-negative number.


Real gases deviate from ideal gas behavior because the intermolecular attractive and repulsive forces cause the motions of the molecules to be correlated. The deviation is especially significant at low temperatures or high pressures, i.e., close to condensation.  A conventional measure for this deviation is the [[Compressibility factor (gases)|compressibility factor]].  
Benoît Mandelbrot discovered<ref>B.B. Mandelbrot: ''The fractal geometry of nature'', Freemann '''(1983)''', ISBN 978-0-716-711-865</ref> that many objects in nature are not strictly classical smooth bodies, but best approximated as fractal sets, i.e. subsets of '''R'''<sup>''N''</sup> whose Hausdorff dimension is strictly greater than its topological dimension.


There are many equations of state available for use with real gases, the simplest of which is the [[van der Waals equation]].


=== Historic background ===
=== Hausdorff measure and dimension ===
Let ''d'' be a non-negative real number and ''S'' ⊂ ''X'' a subset of a metric space (''X'',''ρ'').  The ''d''-dimesional Hausdorff measure of scale ''δ''>0 is
:<math> H^{d*}_\delta(S) := \inf \{\sum_{i=1}^\infty r_i^d : S\subset\bigcup_{i=1}^\infty B_{r_i}(x_i), r_i\le\delta \}</math>
where B<sub>''r''<sub>''i''</sub>(''x''<sub>''i''</sub>) is the open ball around ''x''<sub>''i''</sub> ∈ ''X'' of radius ''r''<sub>''i''</sub>.  The ''d''-dimensional Hausdorff measure is now the limit
:<math> H^{d*}(S) := \lim_{\delta\to0+} H^{d*}_\delta(S)</math>.
As in the Carathéodory construction a set  ''S'' ⊂ ''X'' is called ''d''-measurable iff
:<math> H^{d*}(T) = H^{d*}(S\cap T)+ H^{d*}(T\cap X\setminus S)</math> for all  ''T'' ⊂ ''X''.
A set ''S'' ⊂ ''X'' is called Hausdorff measurable if it is H<sup>''d''</sup>-measurable for all ''d''≥0.


The early work on the behavior of gases began in pre-industrialized [[Europe]] in the latter half of the 17th century by [[Robert Boyle]] who formulated ''[[Boyle's law]]'' in 1662 (independently confirmed by [[Edme Mariotte]] at about the same time).<ref name=Savidge>[http://www.ceesi.com/docs_techlib/events/ishm2003/Docs/1040.pdf Compressibility of Natural Gas] Jeffrey L. Savidge, 78th International School for Hydrocarbon Measurement (Class 1040), 2003. From the website of the Colorado Engineering Experiment Station, Inc. (CEESI).</ref>  Their work on air at low pressures established the inverse relationship between pressure and volume, ''V'' = constant / ''p'' at constant temperature and a fixed amount of air. ''Boyle's Law'' is often referred to as the ''Boyles-Mariotte Law''.
''[[Hausdorff dimension|.... (read more)]]''
 
''[[Ideal gas law|.... (read more)]]''


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Revision as of 07:30, 20 January 2012

Hausdorff dimension

by Melchior Grutzmann (and Brandon Piercy and Hendra I. Nurdin)


In mathematics, the Hausdorff dimension is a way of defining a possibly fractional exponent for all figures in a metric space such that the dimension describes partially the amount to that the set fills the space around it. For example, a plane would have a Hausdorff dimension of 2, because it fills a 2-parameter subset. However, it would not make sense to give the Sierpiński triangle fractal a dimension of 2, since it does not fully occupy the 2-dimensional realm. The Hausdorff dimension describes this mathematically by measuring the size of the set. For self-similar sets there is a relationship to the number of self-similar subsets and their scale.

Informal definition

Intuitively, the dimension of a set is the number of independent parameters one has to pick in order to fix a point. This is made rigorously with the notion of d-dimensional (topological) manifold which are particularly regular sets. The problem with the classical notion is that you can easily break up the digits of a real number to map it bijectively to two (or d) real numbers. The example of space filling curves shows that it is even possible to do this in a continuous (but non-bijective) way.

The notion of Hausdorff dimension refines this notion of dimension such that the dimension can be any non-negative number.

Benoît Mandelbrot discovered[1] that many objects in nature are not strictly classical smooth bodies, but best approximated as fractal sets, i.e. subsets of RN whose Hausdorff dimension is strictly greater than its topological dimension.


Hausdorff measure and dimension

Let d be a non-negative real number and SX a subset of a metric space (X,ρ). The d-dimesional Hausdorff measure of scale δ>0 is

where Bri(xi) is the open ball around xiX of radius ri. The d-dimensional Hausdorff measure is now the limit

.

As in the Carathéodory construction a set SX is called d-measurable iff

for all TX.

A set SX is called Hausdorff measurable if it is Hd-measurable for all d≥0.

.... (read more)