User:John R. Brews/Sample: Difference between revisions
imported>John R. Brews |
imported>John R. Brews No edit summary |
||
Line 44: | Line 44: | ||
</ref> | </ref> | ||
Although these ideas apply to nucleii and other particles, here attention is focused on electrons in atoms. The magnetic moment '''m'''<sub>S</sub> of a system of electrons with spin '''S''' is: | |||
:<math>\mathbf{m_S} = 2m_B \mathbf S \ , </math> | |||
and the magnetic moment '''m'''<sub>L</sub> of an electronic orbital momentum '''L''' is: | |||
:<math>\mathbf{m_L} = m_B \mathbf{L} \ . </math> | |||
Here the factor ''m<sub>B</sub>'' refers to the [[Bohr magneton]], defined by: | |||
:<math>m_B = \frac{e \hbar}{2 m_e} \ , </math> | |||
with ''e'' = the electron charge, ℏ = [[Planck's constant]] divided by 2π, and ''m<sub>e</sub>'' = the electron mass. These relations are generalized using the ''g''-factor: | |||
:<math>\mathbf{m_J} = g m_B \ \mathbf J \ , </math> | |||
with ''g''=2 for spin ('''J''' = '''S''') and ''g''=1 for orbital motion ('''J''' = '''L''').<ref name=Poole> | |||
{{cite book |title=Electron spin resonance: a comprehensive treatise on experimental techniques |author=Charles P. Poole |url=http://books.google.com/books?id=P-4PIoi7Z7IC&pg=PA4 |isbn=0486694445 |year=1996 |publisher=Courier Dover Publications |edition=Reprint of Wiley 1982 2nd ed |pages=p. 4}} | |||
</ref> The resultant total spin '''S''' of an ensemble of electrons in an atom is the vector sum of the constituent spins '''s<sub>j</sub>''': | |||
:<math> \mathbf {S} = \sum_{j=1}^N \ \mathbf{s_j} \ . </math> | |||
Likewise, the orbital momenta of an ensemble of electrons in an atom add as vectors. | |||
Where both spin and orbital motion are present, they combine by vector addition: | |||
:<math>\mathbf{J = L +S} \ ,</math> | |||
and the magnetic moment is | |||
:<math>\mathbf {m_J} = g m_B \mathbf J \ , </math> | |||
with ''g'' now the ''Landé ''g''-factor'' or spectroscopic splitting factor:<ref name=Singh> | |||
{{cite book |title=Introduction To Modern Physics |author=R. B. Singh |url=http://books.google.com/books?id=fd3jyXM-vfMC&pg=PA262 |pages=p. 262 |year=2008 |isbn=8122414087 |publisher=New Age International}} | |||
</ref> | |||
:<math> g = \frac {3}{2} + \frac{S(S+1)-L(L+1)}{2J(J+1)} \ . </math> | |||
====Dynamics==== | ====Dynamics==== |
Revision as of 20:23, 18 December 2010
Magnetic moment
In physics, the magnetic moment of an object is a vector property, denoted here as m, that determines the torque, denoted here by τ, it experiences in a magnetic flux density B, namely τ = m × B (where × denotes the vector cross product). As such, it also determines the change in potential energy of the object, denoted here by U, when it is introduced to this flux, namely U = −m·B.[1]
Origin
A magnetic moment may have a macroscopic origin in a bar magnet or a current loop, for example, or microscopic origin in the spin of an elementary particle like an electron, or in the angular momentum of an atom.
Macroscopic examples
The electric motor is based upon the torque experienced by a current loop in a magnetic field. The basic idea is that the current in the loop is made up of moving electrons, which are subect to the Lorentz force F in a magnetic field:
where e is the electron charge and v is the electron velocity. This force upon the electrons is communicated to the wire loop because the electrons cannot escape the wire, and so exert a force upon it. The electrons at the top of the loop move oppositely to those at the bottom, so the force at the top is opposite in direction to that at the bottom. If the magnetic field is in the plane of the loop, the forces are normal to this plane, causing a torque upon the loop tending to turn the loop about an axis along the direction of the field.[2]
The torque exerted upon a current loop of radius a carrying a current I, placed in a uniform magnetic flux density B at an angle to the unit normal ûn to the loop is:[3]
where the vector S is:
Consequently the magnetic moment of this loop is:
Microscopic examples
At a fundamental level, magnetic moment is related to the angular momentum of fundamental particles. In this discussion, focus is upon the electron and the atom.
The discussion splits naturally into two parts: kinematic and dynamic.
Kinematics
The kinematical discussion, which does not enter upon the physical origins of magnetism and its effects upon mechanics, deals with the classification of atomic states based upon atomic symmetry. It leads to the identification of spin S and orbital angular momentum L and its combination J = L + S.[4]
Although these ideas apply to nucleii and other particles, here attention is focused on electrons in atoms. The magnetic moment mS of a system of electrons with spin S is:
and the magnetic moment mL of an electronic orbital momentum L is:
Here the factor mB refers to the Bohr magneton, defined by:
with e = the electron charge, ℏ = Planck's constant divided by 2π, and me = the electron mass. These relations are generalized using the g-factor:
with g=2 for spin (J = S) and g=1 for orbital motion (J = L).[5] The resultant total spin S of an ensemble of electrons in an atom is the vector sum of the constituent spins sj:
Likewise, the orbital momenta of an ensemble of electrons in an atom add as vectors.
Where both spin and orbital motion are present, they combine by vector addition:
and the magnetic moment is
with g now the Landé g-factor or spectroscopic splitting factor:[6]
Dynamics
The dynamic aspect introduces the proportionality between magnetic moment and angular momentum, the gyromagnetic ratio, and attempts to explain its origin based upon quantum electrodynamics.
Notes
- ↑ V. P. Bhatnagar (1997). A Complete Course in ISC Physics. Pitambar Publishing, p. 246. ISBN 8120902025.
- ↑ For a discussion of the operation of a motor based upon the Lorentz force, see for example, Kok Kiong Tan, Andi Sudjana Putra (2010). Drives and Control for Industrial Automation. Springer, pp. 48 ff. ISBN 1848824246.
- ↑ A. Pramanik (2004). Electromagnetism: Theory and applications. PHI Learning Pvt. Ltd., pp. 240 ff. ISBN 8120319575.
- ↑ The mathematics of this classification is explained masterfully in Hermann Weyl (1950). “Chapter IV A §1 The representation induced in system space by the rotation group”, The theory of groups and quantum mechanics, Reprint of 1932 ed. Courier Dover Publications, pp. 185 ff. ISBN 0486602699. . The application to atomic spectra is explained in great detail in the classic EU Condon and GH Shortley (1935). “Chapter III: Angular momentum”, The theory of atomic spectra. Cambridge University Press, pp. 45 ff. ISBN 0521092094. .
- ↑ Charles P. Poole (1996). Electron spin resonance: a comprehensive treatise on experimental techniques, Reprint of Wiley 1982 2nd ed. Courier Dover Publications, p. 4. ISBN 0486694445.
- ↑ R. B. Singh (2008). Introduction To Modern Physics. New Age International, p. 262. ISBN 8122414087.